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Tanzania [10]
3 years ago
14

It is desired to produce 2.25 grams of dichloromethane (CH2Cl2) by the following reaction. If the percent yield of dichlorometha

ne (CH2Cl2) is 65.5 %, how many grams of carbon tetrachloride would need to be reacted?
______grams carbon tetrachloride

methane (CH4)(g) + carbon tetrachloride(g) dichloromethane (CH2Cl2)(g)
Chemistry
1 answer:
Allushta [10]3 years ago
8 0

Answer:- 3.12 g carbon tetrachloride are needed.

Solution:- The balanced equation is:

CH_4+CCl_4\rightarrow 2CH_2Cl_2

From given actual yield and percent yield we will calculate the theoretical yield that would be further used to calculate the grams of carbon tetrachloride.

percent yield formula is:

percent yield = (\frac{actual}{theoretical})100

65.5=(\frac{2.25}{theoretical})100

theoretical=(\frac{2.25(100)}{65.5})

theoretical = 3.44 g

From balanced equation, there is 2:1 mol ratio between dichloethane and carbon tetrachloride.

Molar mass of dichloroethane is 84.93 gram per mol and molar mass of carbon tetrachloride is 153.82 gram per mol.

3.44gCH_2Cl_2(\frac{1molCH_2Cl_2}{84.93gCH_2Cl_2})(\frac{1molCCl_4}{2molCH_2Cl_2})(\frac{153.82gCCl_4}{1molCCl_4})

= 3.12gCCl_4

So, 3.12 grams of carbon tetrachloride are needed to be reacted.

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Determine ΔH for the reaction CaCO3 → CaO + CO2 given these data: 2 Ca + 2 C + 3 O2 → 2 CaCO3 ΔH = −2,414 kJ C + O2 → CO2 ΔH = −
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The ΔH for the reaction is -456.5 KJ

Explanation:

Here we want to determine ΔH for the reaction;

Mathematically;

ΔH = ΔH(product) - ΔH(reactant)

In the case of the first reaction;

ΔH = ΔH(CaO) + ΔH(CO2) - ΔH(CaCO3)  ...........................(*)

From the other reactions, we can get the respective ΔH for the individual molecule in the reaction

In second reaction;

Kindly note that for elements, molecule of gases, ΔH = 0

What this means is that throughout the solution;

ΔH(Ca)  = 0 KJ

ΔH(O2) = 0 KJ

ΔH(C) = 0 KJ

Thus, in writing the equation for the subsequent chemical reactions, we shall need to write and equate the overall ΔH for the reaction to that of the product alone

So in the second reaction

ΔH = 2ΔH(CaCO3)

Thus;

-2414/2 = ΔH(CaCO3)

ΔH(CaCO3) = -1,207  KJ

Moving to the third reaction, we have;

ΔH = ΔH(CO2)

Hence ΔH(CO2) = -393.5 KJ

For the last reaction;

ΔH = ΔH(CaO)

Hence ΔH(CaO) = -1270 KJ

Going back to equation *

ΔH = ΔH(CaO) + ΔH(CO2) - ΔH(CaCO3)

Using the values of the ΔH  of the respective molecules given above,

ΔH  = -1270 + (-393.5) - (-1207)

ΔH  = -456.5 KJ

8 0
3 years ago
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