Larger molecules will move slower and smaller molecules will move faster. Did this answer your question?
Explanation:
It is given that,
Frequency of monochromatic light, 
Separation between slits, 
(a) The condition for maxima is given by :

For third maxima,



(b) For second dark fringe, n = 2





Hence, this is the required solution.
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(credit to google)
Using the equation E = hc/λ we can find out how much energy a single photon of wavelength 193 nm has. E = Planck Constant * Speed of Light/193 nm