pH of the buffer solution is 1.76.
Chemical dissociation of formic acid in the water:
HCOOH(aq) ⇄ HCOO⁻(aq) + H⁺(aq)
The solution of formic acid and formate ions is a buffer.
[HCOO⁻] = 0.015 M; equilibrium concentration of formate ions
[HCOOH] + [HCOO⁻] = 1.45 M; sum of concentration of formic acid and formate
[HCOOH] = 1.45 M - 0.015 M
[HCOOH] = 1.435 M; equilibrium concentration of formic acid
pKa = -logKa
pKa = -log 1.8×10⁻⁴ M
pKa = 3.74
Henderson–Hasselbalch equation: pH = pKa + log(cs/ck)
pH = 3.74 + log (0.015 M/1.435 M)
pH = 3.74 - 1.98
pH = 1.76
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Answer:
1. The metal atom/ion in these compounds are Ni and Ni2+ respectively.
2. The electrons from s oribital will jump to d orbital and so I expect CO to donate electron pairs in 4p and 4s orbitals and form sp3 hybridisation.
Answer: 
for the reaction is -186.75 J/K
Explanation:
Change in entropy () for the given reaction under standard condition is given by-
= ![[3\times S_{rhombic}^{0}_{(s)}]+[2\times S_{H_{2}O}^{0}_{(g)}]-[2\times S_{H_{2}S}^{0}_{(g)}]-[1\times S_{SO_{2}}^{0}_{(g)}]](https://tex.z-dn.net/?f=%5B3%5Ctimes%20S_%7Brhombic%7D%5E%7B0%7D_%7B%28s%29%7D%5D%2B%5B2%5Ctimes%20S_%7BH_%7B2%7DO%7D%5E%7B0%7D_%7B%28g%29%7D%5D-%5B2%5Ctimes%20S_%7BH_%7B2%7DS%7D%5E%7B0%7D_%7B%28g%29%7D%5D-%5B1%5Ctimes%20S_%7BSO_%7B2%7D%7D%5E%7B0%7D_%7B%28g%29%7D%5D)
So = ![[3\times 31.8 J/K.mol]+[2\times 188.825 J/K.mol]-[2\times 205.79 J/K.mol]-[1\times 248.22 J/K.mol]](https://tex.z-dn.net/?f=%5B3%5Ctimes%2031.8%20J%2FK.mol%5D%2B%5B2%5Ctimes%20188.825%20J%2FK.mol%5D-%5B2%5Ctimes%20205.79%20J%2FK.mol%5D-%5B1%5Ctimes%20248.22%20J%2FK.mol%5D)
= -186.75 J/K
Explanation:
Atoms of metals do not hold their electrons to themselves. Instead they allow them to float around them delocalised. This is important because it is this characteristic that allows metals to be good conductors of electricity since electrons are free to move around to carry a charge.
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