<u>Given:</u>
Mass of solvent water = 4.50 kg
Freezing point of the solution = -11 C
Freezing point depression constant = 1.86 C/m
<u>To determine:</u>
Moles of methanol to be added
<u>Explanation:</u>
The freezing point depression ΔTf is related to the molality m through the constant kf, as follows:
ΔTf = kf*m
where ΔTf = Freezing point of pure solvent (water) - Freezing pt of solution
ΔTf = 0 C - (-11.0 C) = 11.0 C
m = molality = moles of methanol/kg of water = moles of methanol/4.50 kg
11.0 = 1.86 * moles of methanol/4.50
moles of methanol = 26.613 moles
Ans: Thus around 26.6 moles of methanol should be added to 4.50 kg of water.
Answer:
a) K = 5.3175
b) ΔG = 3.2694
Explanation:
a) ΔG° = - RT Ln K
∴ T = 25°C ≅ 298 K
∴ R = 8.314 E-3 KJ/K.mol
∴ ΔG° = - 4.140 KJ/mol
⇒ Ln K = - ( ΔG° ) / RT
⇒ Ln K = - ( -4.140 KJ/mol ) / (( 8.314 E-3 KJ/K.mol )( 298 K ))
⇒ Ln K = 1.671
⇒ K = 5.3175
b) A → B
∴ T = 37°C = 310 K
∴ [A] = 1.6 M
∴ [B] = 0.45 M
∴ K = [B] / [A]
⇒ K = (0.45 M)/(1.6 M)
⇒ K = 0.28125
⇒ Ln K = - 1.2685
∴ ΔG = - RT Ln K
⇒ ΔG = - ( 8.314 E-3 KJ/K.mol )( 310 K )( - 1.2685 )
⇒ ΔG = 3.2694
Answer:
Explanation:
The molecular mass of C2H6 is approximately 30 or [(2 x 12) + (6 x 1)]. Therefore the molecule is about 2.5 times as heavy as the 12C atom or about the same mass as the NO atom with a molecular mass of 30 or (14+16).
F BLOCK is the block on the period table that contains the actinide series of elements.
Actinide series of elements are two rows under the periodic table which include Lanthanide series and Actinide series. These are all radioactive elements and all of these are not not found in nature. All these are included in F block element.
0.000132 g of hydrated sodium borate (Na₂B₄O₇ · 10 H₂O)
Explanation:
First we need to find the number of moles of sodium borate (Na₂B₄O₇) in the solution:
molar concentration = number of moles / volume (L)
number of moles = molar concentration × volume (L)
number of moles of Na₂B₄O₇ = 0.1 × 0.5 = 0.05 moles
We know now that we need 0.05 moles of hydrated sodium borate (Na₂B₄O₇ · 10 H₂O) to make the solution.
Now to find the mass of hydrated sodium borate we use the following formula:
number of moles = mass / molar weight
mass = number of moles × molar weight
mass of hydrated sodium borate = 0.05 / 381 = 0.000132 g
Learn more about:
molar concentration
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