Answer:
The barrier has to be 34.23 kJ/mol lower when the sucrose is in the active site of the enzyme
Explanation:
From the given information:
The activation barrier for the hydrolysis of sucrose into glucose and fructose is 108 kJ/mol.
In this same concentration for the glucose and fructose; the reaction rate can be calculated by the rate factor which can be illustrated from the Arrhenius equation;
Rate factor in the absence of catalyst:
Rate factor in the presence of catalyst:
Assuming the catalyzed reaction and the uncatalyzed reaction are taking place at the same temperature :
Then;
the ratio of the rate factors can be expressed as:
![\dfrac{k_2}{k_1}={ \dfrac {e^{[ Ea_1 - Ea_2 ] }}{RT} }}](https://tex.z-dn.net/?f=%5Cdfrac%7Bk_2%7D%7Bk_1%7D%3D%7B%20%20%5Cdfrac%20%7Be%5E%7B%5B%20%20Ea_1%20-%20Ea_2%20%5D%20%7D%7D%7BRT%7D%20%7D%7D)
Thus;
Let say the assumed temperature = 25° C
= (25+ 273)K
= 298 K
Then ;
The barrier has to be 34.23 kJ/mol lower when the sucrose is in the active site of the enzyme
Answer:
a. Phosphoric Acid
b. Acetic Acid
c. Hypochlorous Acid
Explanation:
A buffer works when the pH of this one is in pKa ± 1. That means, to find which buffer system works in some pH you need to find pKa:
pKa = -log Ka
<em>pKa Acetic acid:</em>
-log1.8x10⁻⁵ = 4.74
<em>pKa phosphoric acid:</em>
-log7.5x10⁻³ = 2.12
<em>pKa hypochlorous acid:</em>
-log3.5x10⁻⁸ = 7.46
a. For a pH of 2.8 the best choice is phophoric acid because its effective range is: 1.12 - 3.12 and 2.8 is between these values.
b. pH 4.5. Acetic acid. effective between pH's 3.74 - 5.74
c. pH 7.5. Hypochlorous acid that works between 6.46 and 8.46
Answer:
C.) 35
Explanation:
The mass is made up of the total protons and neutrons in an atom. Protons and neutrons both have a mass of 1 amu. Electrons are not included in this measurement because they have an insignificant mass (practically 0).
(17 protons x 1 amu) + (18 neutrons x 1 amu) = 35 amu
Therefore, if an atom contains 17 protons and 18 neutrons, the mass should be 35 amu.
In an electrically neuteral atom, number of protons = number of electrons = atomic number.
Mass number = neutrons + protons/electrons/atomic number
Therefore,
neutrons = mass number - <span>protons/electrons/atomic number
Neutrons = 33 - 15 = 18
The answer is thus B. But this is the solution and explanation along with it as proof.</span>
