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Verdich [7]
2 years ago
10

Which of the following is not a valid set of quantum numbers

Chemistry
2 answers:
zhuklara [117]2 years ago
7 0

Answer:  C. n = 3, l = 3, m = 3

Explanation:

1. Principle Quantum Numbers: This quantum number describes the size of the orbital. It is represented by n. n = 1,2,3,4....

2. Azimuthal Quantum Number: This quantum number describes the shape of the orbital. It is represented as 'l'. The value of l ranges from 0 to (n-1). For l = 0,1,2,3... the orbitals are s, p, d, f...

3. Magnetic Quantum Number: This quantum number describes the orientation of the orbitals. It is represented as m_l. The value of this quantum number ranges from (-l\text{ to }+l). When l = 2, the value of m_l will be -2, -1, 0, +1, +2.

A.  n = 2, l = 1 , m = 0 is possible.

B. n = 1, l = 0, m = 0   is possible.

C. n = 3, l = 3, m = 3 is not possible as for n = 3, l = 0, 1 and 2 and m = 0,+1, +2, -1 and -2.

ASHA 777 [7]2 years ago
3 0
I believe the answer is C, n = 3, l = 3, m = 3. The magnetic quantum number, or 

<span>ml</span>, can only take values that range from <span>−l</span> to <span>+l</span>, as you can see in the table above.

For option C), the angular momentum quantum number of equal to ++2<span>, which means that <span>ml</span> can have a maximum value of </span>+2<span>. Since it is given as having a value of </span>+3**, this set of quantum numbers is not a valid one.

The other three sets are valid and can correctly describe an electron.

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How many liters of hydrogen gas will be produced at STP from the reaction of 7.179×10^23 atoms of magnesium with 54.219g of phos
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Answer: The volume of hydrogen gas produced will be, 12.4 L

Explanation : Given,

Mass of H_3PO_4 = 54.219 g

Number of atoms of Mg = 7.179\times 10^{23}

Molar mass of H_3PO_4 = 98 g/mol

First we have to calculate the moles of H_3PO_4 and Mg.

\text{Moles of }H_3PO_4=\frac{\text{Given mass }H_3PO_4}{\text{Molar mass }H_3PO_4}

\text{Moles of }H_3PO_4=\frac{54.219g}{98g/mol}=0.553mol

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\text{Moles of }Mg=\frac{7.179\times 10^{23}}{6.022\times 10^{23}}=1.19mol

Now we have to calculate the limiting and excess reagent.

The balanced chemical equation is:

3Mg+2H_3PO_4\rightarrow Mg(PO_4)_2+3H_2

From the balanced reaction we conclude that

As, 3 mole of Mg react with 2 mole of H_3PO_4

So, 0.553 moles of Mg react with \frac{2}{3}\times 0.553=0.369 moles of H_3PO_4

From this we conclude that, H_3PO_4 is an excess reagent because the given moles are greater than the required moles and Mg is a limiting reagent and it limits the formation of product.

Now we have to calculate the moles of H_2

From the reaction, we conclude that

As, 3 mole of Mg react to give 3 mole of H_2

So, 0.553 mole of Mg react to give 0.553 mole of H_2

Now we have to calculate the volume of H_2  gas at STP.

As we know that, 1 mole of substance occupies 22.4 L volume of gas.

As, 1 mole of hydrogen gas occupies 22.4 L volume of hydrogen gas

So, 0.553 mole of hydrogen gas occupies 0.553\times 22.4=12.4L volume of hydrogen gas

Therefore, the volume of hydrogen gas produced will be, 12.4 L

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