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Dafna1 [17]
2 years ago
14

A large balloon contains 5400 m3 of He gas that is kept at a temperature of 280 K and an absolute pressure of 1.10 x 105 Pa. Fin

d the mass of He inside the balloon. (Molar mass of He : 4.002 g/mol)
Chemistry
1 answer:
patriot [66]2 years ago
8 0

Answer:

1.02 × 10⁶ g

Explanation:

Step 1: Given data

  • Volume of the balloon (V): 5400 m³
  • Temperature (T): 280 K
  • Absolute pressure (P): 1.10 × 10⁵ Pa
  • Molar mass of He (M): 4.002 g/mol

Step 2: Convert "V" to L

We will use the conversion factor 1 m³ = 1000 L.

5400 m³ × 1000 L/1 m³ = 5.400 × 10⁶ L

Step 3: Convert "P" to atm

We will use the conversion factor 1 atm = 101325 Pa.

1.10 × 10⁵ Pa × 1 atm / 101325 Pa = 1.09 atm

Step 4: Calculate the moles of He (n)

We will use the ideal gas equation.

P × V = n × R × T

n = P × V / R × T

n = 1.09 atm × 5.400 × 10⁶ L / 0.08206 atm.L/mol.K × 280 K

n = 2.56 × 10⁵ mol

Step 5: Calculate the mass of He (m)

We will use the following expression.

m = n × M

m = 2.56 × 10⁵ mol × 4.002 g/mol

m = 1.02 × 10⁶ g

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Answer : The energy removed must be, 29.4 kJ

Explanation :

The process involved in this problem are :

(1):C_6H_6(l)(322K)\rightarrow C_6H_6(l)(279K)\\\\(2):C_6H_6(l)(279K)\rightarrow C_6H_6(s)(279K)\\\\(3):C_6H_6(s)(279K)\rightarrow C_6H_6(s)(205K)

The expression used will be:  

Q=[m\times c_{p,l}\times (T_{final}-T_{initial})]+[m\times \Delta H_{fusion}]+[m\times c_{p,s}\times (T_{final}-T_{initial})]

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c_{p,s} = specific heat of solid benzene = 1.51J/g^oC=1.51J/g.K

c_{p,l} = specific heat of liquid benzene = 1.73J/g^oC=1.73J/g.K

\Delta H_{fusion} = enthalpy change for fusion = -9.8kJ/mol=-\frac{9.8\times 1000J/mol}{78g/mol}=-125.6J/g

Now put all the given values in the above expression, we get:

Q=[94.4g\times 1.73J/g.K\times (279-322)K]+[94.4g\times -125.6J/g]+[94.4g\times 1.51J/g.K\times (205-279)K]

Q=-29427.312J=-29.4kJ

Negative sign indicates that the heat is removed from the system.

Therefore, the energy removed must be, 29.4 kJ

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