Answer:
k = 4.21 * 10⁻³(L/(mol.s))
Explanation:
We know that
k = Ae ------------------- euqation (1)
K= rate constant;
A = frequency factor = 4.36 10^11 M⁻¹s⁻¹;
E = activation energy = 93.1kJ/mol;
R= ideal gas constant = 8.314 J/mol.K;
T= temperature = 332 K;
Put values in equation 1.
k = 4.36*10¹¹(M⁻¹s⁻¹)e
k = 4.2154 * 10⁻³(M⁻¹s⁻¹)
here M =mol/L
k = 4.21 * 10⁻³((mol/L)⁻¹s⁻¹)
or
k = 4.21 * 10⁻³((L/mol)s⁻¹)
or
k = 4.21 * 10⁻³(L/(mol.s))
Answer:
Stat PVC = Stat(82+98.5)
Stat PVT = Stat(59+71.5)
Explanation
PVI = 71 + 35
Let G1 = Grade 1; G2 = Grade 2
G1 = +2.1% ; G2 = -3.4%
Highest point of curve at station = 74 + 10
General equation of a curve:
At highest point of the curve
Station PVT
Answer:
Amount of air left in the cylinder=m=0.357 Kg
The amount of heat transfer=Q=0
Explanation:
Given
Initial pressure=P1=300 KPa
Initial volume=V1=0.2
Initial temperature=T=20 C
Final Volume==0.1
Using gas equation
m1==(300*0.2)/(.287*293)
m1=0.714 Kg
Similarly
m2=(P2*V2)/R*T2
m2=(300*0.1)/(0.287*293)
m2=0.357 Kg
Now calculate mass of air left,where me is the mass of air left.
me=m2-m1
me=0.715-0.357
mass of air left=me=0.357 Kg
To find heat transfer we need to apply energy balance equation.
Where me=m1-m2
And as the temperature remains constant,hence the enthalpy also remains constant.
h1=h2=he=h
Q=(me-(m1-m2))*h
me=m1-me
Thus heat transfer=Q=0