The only current flowing in the circuit is supplied by the 100 V source. Its only load is the 40+60 ohm series circuit attached, so the current in that loop is (100V)/(40+60Ω) = 1A. That means V1 = (1A)(60Ω) = 60V.
Vab will be the sum of voltages around the right-side "loop" between terminals 'a' and 'b'. It is (working clockwise from terminal 'b') ...
