I got that pH=3.65 using the fact that Ka=[H⁺][A⁻]/[HA] at equilibrium. In the ice table, I stands for initial, C stands for change, and E stands for equilibrium.
I hope this helps. Let me know if anything is unclear.
Answer:

Explanation:
Half time is period required to desintegrating the half of the initial number of atoms. Then, the total time is:


Answer: The bonds are intermediate between double and single bonds
Explanation:
A closer look at the diagram below shows that the bonds in sulphur IV oxide are intermediate between double and single bonds. Hence they do not have the exact bond angle of single bonds. This is why the bond angle is not exactly 120°. There are two resonance structures in the diagram that clearly show this point.
Divide this problem in to two steps: 1. Convert millimoles to moles. 2. Convert moles to grams.
1.
2.65 mlmol x 1mol/1000mlmol=.00265mol
2.
.00265mol x 32.065g/1 mol=.0850g S
Let me know if you need more explanation on why I used the conversions that I did.