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Olenka [21]
3 years ago
14

When a solution of barium nitrate and a solution of copper (II) sulfate are mixed, a chemical reaction produces solid barium sul

fate, which sinks to the bottom, and a solution of copper (II) nitrate. Suppose some barium nitrate is dissolved in 120.00 g of water and 8.15 g of copper (II) sulfate is dissolved in 75.00 g of water. The solutions are poured together, and a white solid forms. After the solid is filtered off, it is found to have a mass of 10.76 g. The mass of the solution that passed through the filter is 204.44 g. What mass of barium nitrate was used in the reaction?
Chemistry
2 answers:
Artemon [7]3 years ago
8 0
The total mass of the products is 10.76 g + 204.44 g = 215.20 g.
The masses of all the reactants but one are known so,

215.20 g - 120.00 g - 8.15 g - 75.00 g = 12.05 g

12.05 g is the mass of the unweighed barium nitrate. 
Arturiano [62]3 years ago
5 0

Mass of barium nitrate used in the beginning of the reaction was \boxed{12.05{\text{ g}}}.

Further explanation:

The chemical reaction that contains equal number of atoms of the different elements in the reactant as well as in the product side is known as balanced chemical reaction. The chemical equation is required to be balanced to follow the Law of the conservation of massThe chemical reaction that contains equal number of atoms of the different elements in the reactant as well as in the product side is known as balanced chemical reaction. The chemical equation is required to be balanced to follow the Law of the conservation of mass.

Every chemical reaction occurs in accordance with the law of conservation of mass that states that total mass of the reactant combining must be equal to the products formed. Hence every balanced chemical equation must obey the law of conservation of mass and energy.

The balanced chemical equation for reaction between barium nitrate and copper sulfate is given as follows:

{\text{BaN}}{{\text{O}}_3}\left( l \right) + {\text{CuS}}{{\text{O}}_4}\left( l \right) \to {\text{BaS}}{{\text{O}}_4}\left( s \right) + {\text{CuN}}{{\text{O}}_3}\left( l \right)  

Since the mass of the solution that passed through the filter was 215.20{\text{ g}}, and the mass of solid {\text{BaS}}{{\text{O}}_4} precipitate separated was  {\text{10}}{\text{.76 g}}. Hence total mass of products is the sum of these two reactants.

\begin{aligned}{\left( {{\text{Total}}\;{\text{Mass}}} \right)_{{\text{products}}}} &= {\text{10}}{\text{.76 g}} + 215.20{\text{ g}}\\&= 215.20{\text{ g}}\\\end{aligned}

Assume the mass of unknown barium nitrate is x . Mass of reactants involves mass of barium nitrate, water used for dissolving barium nitrate, mass of copper sulfate and water used for dissolving copper sulfate. The total mass of reactants is calculated as follows:

 \begin{aligned}{\left( {{\text{Total Mass}}} \right)_{{\text{reactants}}}}&= x + {\text{8}}{\text{.15 g}} + {\text{120}}{\text{.0 g}} + {\text{75}}{\text{.00 g}}\\&= x + 203.15\;{\text{g}}\\\end{aligned}

The law of conservation of mass holds true for this equation as well as represented below:

{\left( {{\text{Total Mass}}} \right)_{{\text{reactants}}}} = {\left( {{\text{Total}}\;{\text{Mass}}} \right)_{{\text{products}}}}                                     …… (1)

Substitute 215.20{\text{ g}} for {\left( {{\text{Total}}\;{\text{Mass}}} \right)_{{\text{products}}}} and x + 203.15\;{\text{g}} for {\left( {{\text{Total Mass}}} \right)_{{\text{reactants}}}} in equation

(1).

 x + {\text{120}}{\text{.0 g}} + {\text{75}}{\text{.00 g}} + {\text{8}}{\text{.15 g}} = 215.20{\text{ g}}

Simplify to obtain the value of mass of barium nitrate \left( x \right).

 \begin{aligned}x&=215.20{\text{ g}}- {\text{120}}{\text{.0 g}} - {\text{75}}{\text{.00 g}} - {\text{8}}{\text{.15 g}}\\&= 215.20{\text{ g}} - {\text{203}}{\text{.15 g}}\\&= 12.05{\text{ g}}\\\end{aligned}

Learn more:

1. Effectiveness of detergent: brainly.com/question/10136601

2. The main purpose of conducting experiments: brainly.com/question/5096428

Answer details:  

Grade: High School

Subject: Chemistry

Chapter: Chemical equations and reactions.

Keywords: Barium nitrate, precipitation, precipitate, law of conservation of mass, mass, products, reactants and 12.05 g.

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Answer:

a. 4 C_3H_5N_3O_9 (l)\rightarrow 6N_2 (g) + O_2 (g) + 10 H_2O (g) + 12 CO_2 (g)

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Question 1 (a). Just as the problem states, liquid nitroglycerin decomposes into nitrogen gas N_2, oxygen gas O_2, water vapor H_2O and carbon dioxide CO_2. Let's write the decomposition of nitroglycerin into these 4 components:

C_3H_5N_3O_9 (l)\rightarrow N_2 (g) + O_2 (g) + H_2O (g) + CO_2 (g)

Now we need to balance the equation. Firstly, notice we have 3 carbon atoms on the left and 1 on the right, so let's multiply carbon dioxide by 3:

C_3H_5N_3O_9 (l)\rightarrow N_2 (g) + O_2 (g) + H_2O (g) + 3 CO_2 (g)

Now, we have 3 nitrogen atoms on the left and 2 on the right, so let's multiply nitrogen on the right by \frac{3}{2}:

C_3H_5N_3O_9 (l)\rightarrow \frac{3}{2}N_2 (g) + O_2 (g) + H_2O (g) + 3 CO_2 (g)

We have 5 hydrogen atoms on the left, 2 on the right, so let's multiply the right-hand side by \frac{5}{2}:

C_3H_5N_3O_9 (l)\rightarrow \frac{3}{2}N_2 (g) + O_2 (g) + \frac{5}{2} H_2O (g) + 3 CO_2 (g)

Finally, count the oxygen atoms. We have a total of 9 on the left. On the right we have (excluding oxygen molecule):

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This leaves 9 - 8.5 = 0.5 = \frac{1}{2} of oxygen. Since oxygen is diatomic, we need to take one fourth of it to get one half in total:

C_3H_5N_3O_9 (l)\rightarrow \frac{3}{2}N_2 (g) + \frac{1}{4} O_2 (g) + \frac{5}{2} H_2O (g) + 3 CO_2 (g)

To make it look neater without fractional coefficients, multiply both sides by 4:

4 C_3H_5N_3O_9 (l)\rightarrow 6N_2 (g) + O_2 (g) + 10 H_2O (g) + 12 CO_2 (g)

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Firstly, we may find moles of carbon dioxide produced using the ideal gas law pV = nRT.

Rearranging for moles, that is, dividing both sides by RT (here R is the ideal gas law constant):

n_{CO_2} = \frac{pV_{CO_2}}{RT} = \frac{1 atm\cdot 41.0 L}{0.08206 \frac{L atm}{mol K}\cdot 259.15 K} = 1.928 mol

According to the stoichiometry of the balanced chemical equation:

4 C_3H_5N_3O_9 (l)\rightarrow 6N_2 (g) + O_2 (g) + 10 H_2O (g) + 12 CO_2 (g)

4 moles of nitroglycerin (ng) produce 12 moles of carbon dioxide. From here we can find moles o nitroglycerin knowing that:

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Multiplying the number of moles of nitroglycerin by its molar mass will yield the mass of nitroglycerin decomposed:

m_{ng} = n_{ng}\cdot M_{ng} = 0.6427 mol\cdot 227.09 g/mol = 146.0 g

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